PROPERTIES OF IONIC LIQUIDS

The properties of an ionic liquid such as solubility, viscosity and, of course price, can be varied by changing the nature of the cation/anion combination, so that ionic liquids have been described as designer solvents.

They have intrinsically useful properties which have attracted enormous attention from academic and industrial researchers alike. Their non-measurable vapour pressure and non-flammability makes them attractive candidates for the implementation of safer processes so that they are regarded as eco-friendly alternatives to volatile organic compounds (VOCs).

The excellent dissolution properties for a lot of organic and inorganic substrates allow smaller plant sizes and increased space-time-yields. Additionally, ionic liquids have high thermal stabilities, allowing higher reaction temperatures. They also permit a range of separation techniques such as distillation or sublimation which are sometimes not possible using traditional organic solvents.

Electrochemical applications benefit from their good electrical conductivities in wide electrochemical windows. Other beneficial properties include enhanced enzyme stability, improved chemo-selectivity and easier catalyst recovery and recycling.

Ionic liquids are sometimes thought to be corrosive media. In response to our customers' demand for halogenfree ionic liquids (no corrosion problems associated with the formation of HF, improved options for end-of-life disposal) Solvent Innovation has recently launched their ECOENGTM -family, comprising of halogenfree anions based on sulfate or phosphate.

Due to the above mentioned tunability of properties it is possible to find the best suitable ionic liquid for a given application or even to design new cation-anion combinations based on our long-term experience on ionic liquids.

To summarize ionic liquids have the following advantageous properties

  • No measurable vapor pressure
  • Non-flammable below their decomposition temperature
  • Tunable properties
  • Excellent solvation properties for a variety of organic and inorganic compounds
  • High electric conductivities
  • High thermal stabilities
  • Wide liquidus range

 

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NEWS
2008-01-17Solvent Innovation now part of Merck KGaA

2007-07-02Solvent Innovation obtains US license for bis(trifluoromethylsulfonyl)imide ionic liquids

2006-12-11Solvent Innovation releases new product list

2006-10-09Solvent Innovation now offers bis(trifluoromethylsulfonyl)imide ionic liquids

2006-06-22Solvent Innovation welcomes participants of the DFG-program on ionic liquids

2006-04-06Solvent Innovation offers a unique quality of 1-Ethyl-3-methyl-imidazolium methanesulfonate

2005-12-02Solvent Innovation congratulates Prof. Dr. Peter Wasserscheid on the receipt of the Leibniz award 2006

2005-10-10Solvent Innovation increases production capacities up to 20 t/year